Well John, in reality, are the granules just a vehicle for carrying the chemical compound that makes it all work anyway?
Granules really have nothing to do with the performance of the powder, except for ease of volume reloading into small narrow necked cartridges, doesn't it?
The size and shape of the granules have a lot to do with burning characteristics.
Roughly speaking, for three dimensional objects, volume grows as the cube of the dimensions, whereas surface area grows as the square. So for two granules of the same shape, the smaller one has a higher surface area to mass ratio, and hence burns relatively faster than just its lesser mass would indicate.