By the time the concrete crew leaves your sidewalk should be pretty well set up and able to withstand hoof prints, I would think.
Sounds like a nice improvement, logger. Good luck!
This^ Unless it’s cold, it will set up in a few hours, although it continues curing for over a month. Once finished, they should spray it with a retarder and cover it with plastic. The next day, they will come back and spray it off with a water hose to expose to aggregate. I wouldn’t think deer would brave the concrete crew nor the plastic sheeting to walk on it before it hardens sufficiently.