It doesn't work that way. Changing the shoulder shape and straightening the body does not allow you to run higher pressure. You could've run that same pressure in a standard 223 case as well.

I'm guessing most 223 AI reamers cut a longer throat though, more like 223 Wylde? That accounts for a lot more potential velocity difference than the minimal change in case capacity. Similar to comparing 223 Rem and 5.56 loads.