I find that my Merino t-shirts itch just a bit until I get a sweat going. Dry skin I suppose.
I like a lightweight T shirt under a mid-weight long-sleeve, or 1/4 zip for layering,
Change out the T-shirt & boxers after a day or two.
With daily sponge baths etc. of course.
For higher intensity sweat intensive activities like XC skiing, I still prefer layering synthetic grid fleece of appropriate weights for the temperatures encountered.
But nothing beats the comfort of Merino.