Hello Guys - Great thread.
I'm wondering about the acid based solutions and the "nails" that are specified when formulating these. I assume we are talking here of "iron" nails - is this so ?? If one didn't have any known "iron" nails to hand what would be the best subsitute - ordinary cast iron pieces ?? Wrought iron pieces ?? steel nails ??
Cheers - Foster
Howe's Book,
The Modern Gunsmith lists 20 browning/bluing solutions. Most of them contain ferric chloride and corrosive sublimate, along with other ingredients. Formula #6 consists of a combination of nitric and hydrochloric acids, to which are added steel chips or iron nails. After the iron completely dissolves, distilled water is added and the solution is allowed to stand (in a blue bottle) for 2 days (!).
I think the iron nails basically form Ferric Chloride when dissolved in hydrochloric acid (HCl). The corrosive sublimate is Mercury(IV)Chloride and is VERY nasty stuff. I refuse to have anything to do with it. I always use a solution that doesn't contain it.
Iron, steel are pretty much ok for making bluing solution. You must avoid galvanized nails, as the zinc plating will wreak havoc with your process.