Yup, yup yup, wife makes a great stove top braised pot roast in enameled dutch oven. I know you got that nice one from Big Jim.
Brown roast in a little oil on all sides before adding liquid and cooking covered on low for a few hours. I like mine really dark brown before braising.
Heres a good basic recipe from Tyler Perry. Reminds me of the pot roasts mom used to make.
https://www.foodnetwork.com/recipes/tyler-florence/braised-pot-roast-with-vegetables-recipe-1914232