I noticed Costco now has poly/merino wool underwear for about $18 each. Should work good.
I usually wear poly underwear, blue jeans and have rain gear with me. I make it a point though to stay dry. I don't hunt in the rain and hole up if it is snowing. I found out a long time ago, elk hole up in a snow storm but you had best be out there right away after it stops snowing.