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I can remember at least two head-on shots when I aimed right between the eyes, looking at the skull I bet it glanced off.
About 90% of my shots are when they are swimming past and I have aimed at the center of mass about at the water line. I am sighted in for 25 yards but at 10-15 I would be a little high.
I picked up the Horton crossbow off the classifieds so I may try another form of attack pretty soon. My Gold Tips float and I am hoping the crossbow bolts do the same.